Stadium: Table 3 Round: 4
| WTT Feeder Dusseldorf XD | 2023/02/15 09:00 | Robles/Xiao v Piccolin/Stoyanov | L | 3-2 |
| WTT Contender Doha XD Quals | 2023/01/16 17:50 | Diaconu/Pletea v Piccolin/Stoyanov | L | 3-1 |
| WTT Contender Novo Gorica XD | 2022/11/03 13:00 | Piccolin/Stoyanov v Diaconu/Pletea | L | 0-3 |
| WTT Feeder Panagyurishte XD | 2022/09/02 06:30 | Krastev/Yovkova v Piccolin/Stoyanov | L | 3-0 |
| WTT Feeder Olomouc XD | 2022/08/25 08:35 | Chen/Mischek v Piccolin/Stoyanov | L | 3-1 |
| European Championships XD | 2022/08/14 08:05 | Piccolin/Stoyanov v Ni/Mladenovic | L | 2-3 |
| WTT Feeder Westchester XD | 2022/05/12 14:00 | Piccolin/Laurenti v Piccolin/Stoyanov | L | 3-2 |
| World Championship XD | 2021/11/25 16:10 | Doo/Wong v Piccolin/Stoyanov | L | 3-0 |